Effect of the leaching of calcium hydroxide from cement paste on mechanical and physical properties
Autor: | Raoul François, Christophe Carde |
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Přispěvatelé: | Laboratoire Matériaux et Durabilité des constructions (LMDC), Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA) |
Jazyk: | angličtina |
Rok vydání: | 1997 |
Předmět: |
Cement
Calcium hydroxide Materials science Ammonium nitrate 0211 other engineering and technologies technology industry and agriculture Mineralogy 02 engineering and technology Building and Construction 021001 nanoscience & nanotechnology equipment and supplies chemistry.chemical_compound [SPI.GCIV]Engineering Sciences [physics]/Civil Engineering Compressive strength chemistry 021105 building & construction General Materials Science Leaching (metallurgy) Mortar Composite material 0210 nano-technology Porosity Dissolution |
Zdroj: | Cement and Concrete Research Cement and Concrete Research, 1997, 27 (4), pp.539-550. ⟨10.1016/S0008-8846(97)00042-2⟩ Cement and Concrete Research, Elsevier, 1997, 27 (4), pp.539-550. ⟨10.1016/S0008-8846(97)00042-2⟩ |
ISSN: | 0008-8846 |
DOI: | 10.1016/S0008-8846(97)00042-2⟩ |
Popis: | This paper deals with the effect of the leaching process of cement based materials on their mechanical and physical properties. In order to characterize this effect, we have performed experiments on cement paste samples. The leaching process was achieved by the use of a 50% concentrate solution of ammonium nitrate. Both compression tests and water porosity tests were conducted on micro-cylinder samples (10, 12, 14 and 20 mm of diameter) because of the slow kinetics of degradation due to the leaching. The deterioration of the cement paste and the mortar exposed to the action of the ammonium nitrate was manifested by a peripheral zone of less resistance. This process induces mainly a total leaching of Ca(OH)2 and a progressive decalcification of CS H which leads to a gradient of C S ratio in the leaching zone. Both mechanical tests and water porosity tests show that there is a linear variation of the loss of strength and the increase in porosity in relation to the ratio of degraded area over total area of the sample A d A t . It means that both compressive resistance and water porosity of the leaching zone are constant whatever the size of the degraded zone and then whatever the time of exposure to the chemical attack. So we could venture the hypothesis that the dissolution of calcium hydroxide is the essential parameter governing both decrease in strength and increase in porosity. |
Databáze: | OpenAIRE |
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