Synthesis and properties of poly(1,4-cyclohexanedimethylene-co-isosorbide terephthalate), a biobased copolyester with high performances
| Autor: | Nicolas Jacquel, Helene Amedro, Jean-Pierre Pascault, René Saint-Loup, Sylvain Legrand, Alain Rousseau, Françoise Fenouillot |
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| Přispěvatelé: | Roquette Frères, Ingénierie des Matériaux Polymères (IMP), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université Jean Monnet [Saint-Étienne] (UJM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Isosorbide Polymers and Plastics General Physics and Astronomy 02 engineering and technology 010402 general chemistry 01 natural sciences [SPI.MAT]Engineering Sciences [physics]/Materials Materials Chemistry medicine Reduced viscosity ComputingMilieux_MISCELLANEOUS chemistry.chemical_classification Molar mass Organic Chemistry Polymer 021001 nanoscience & nanotechnology Copolyester 0104 chemical sciences Amorphous solid Polyester [CHIM.POLY]Chemical Sciences/Polymers Chemical engineering chemistry 0210 nano-technology Glass transition medicine.drug |
| Zdroj: | European Polymer Journal European Polymer Journal, Elsevier, 2019, 115, pp.22-29. ⟨10.1016/j.eurpolymj.2019.03.018⟩ |
| ISSN: | 0014-3057 1873-1945 |
| DOI: | 10.1016/j.eurpolymj.2019.03.018 |
| Popis: | In this paper, the synthesis and properties of poly(1,4-cyclohexanedimethylene-co-isosorbide terephthalate) (PCIT) with isosorbide (IS) content ranging from 16 to 61 mol% relative to the total diols amount were investigated. Amorphous polymers were successfully synthesized without isosorbide ring hydration. Glass transition temperature (Tg) linearly increased of 1.1 °C for each molar percent of isosorbide included in the polyester, meanwhile melting temperature (Tm) linearly decreased of 2.1 °C for semi-crystalline samples (up to 25 mol% of isosorbide). Molar masses of semi-crystalline samples were easily increased using high temperature solid-state polymerization (SSP) and reduced viscosity (ηred) higher than 70 mL g−1 were obtained. Semi-crystalline samples exhibit outstanding impact resistance compared with commercial high performance copolyester, whereas amorphous copolyesters exhibit acceptable mechanical properties coupled with high thermal resistance. Results confirmed the promising association between isosorbide and 1,4-cyclohexanedimethanol to reach tunable thermal and mechanical properties, depending on the targeted applications. |
| Databáze: | OpenAIRE |
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