XAS/DRIFTS/MS spectroscopy for time-resolved operando investigations at high temperature
Autor: | François Perrin, Frederic Meunier, Bernard Gorges, Manuel Monte, Sebastien Pasternak, Sakura Pascarelli, G. Berruyer, Trevor Mairs, Hugo Vitoux, Ana Iglesias-Juez, Olivier Mathon, Giovanni Agostini, Debora Motta Meira, Marcos Fernández-García |
---|---|
Přispěvatelé: | European Synchrotron Radiation Facility (ESRF), IRCELYON-Ingéniérie, du matériau au réacteur (ING), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Nuclear and High Energy Physics
operando measurements Materials science Diffuse reflectance infrared fourier transform Absorption spectroscopy Analytical chemistry Nanoparticle 02 engineering and technology 010402 general chemistry Mass spectrometry 7. Clean energy 01 natural sciences high temperature Spectroscopy Instrumentation [PHYS]Physics [physics] X-ray absorption spectroscopy Radiation operandomeasurements 021001 nanoscience & nanotechnology [SDE.ES]Environmental Sciences/Environmental and Society Research Papers 0104 chemical sciences Characterization (materials science) small-dead-volume cells Absorption edge combination XAS/DRIFT/MS 0210 nano-technology |
Zdroj: | Journal of Synchrotron Radiation Journal of Synchrotron Radiation, International Union of Crystallography, 2018, 25 (---), pp.1745-1752. ⟨10.1107/S160057751801305X⟩ 'Journal of Synchrotron Radiation ', vol: 25, pages: 1745-1752 (2018) |
ISSN: | 1600-5775 0909-0495 |
Popis: | A new reactor cell and experimental setup designed to perform time-resolved experiments on heterogeneous catalysts under working conditions that simulltaneously combines XAS, DRIFT and MS spectroscopies are reported. The combination of complementary techniques in the characterization of catalysts under working conditions is a very powerful tool for an accurate and in-depth comprehension of the system investigated. In particular, X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and mass spectroscopy (MS) is a powerful combination since XAS characterizes the main elements of the catalytic system (selecting the absorption edge) and DRIFTS monitors surface adsorbates while MS enables product identification and quantification. In the present manuscript, a new reactor cell and an experimental setup optimized to perform time-resolved experiments on heterogeneous catalysts under working conditions are reported. A key feature of this setup is the possibility to work at high temperature and pressure, with a small cell dead volume. To demonstrate these capabilities, performance tests with and without X-rays are performed. The effective temperature at the sample surface, the speed to purge the gas volume inside the cell and catalytic activity have been evaluated to demonstrate the reliability and usefulness of the cell. The setup capability of combining XAS, DRIFTS and MS spectroscopies is demonstrated in a time-resolved experiment, following the reduction of NO by Rh nanoparticles supported on alumina. |
Databáze: | OpenAIRE |
Externí odkaz: | |
Nepřihlášeným uživatelům se plný text nezobrazuje | K zobrazení výsledku je třeba se přihlásit. |