Ion‐Size‐Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
| Autor: | Ulrich S. Schubert, Christine Artner, Matthias Czakler, Stefan Kronister |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Lanthanide
chemistry.chemical_element Nanotechnology 02 engineering and technology Carboxylate ligands 010402 general chemistry Methacrylate 01 natural sciences Lanthanides Ion Inorganic Chemistry chemistry.chemical_compound Cluster (physics) Titanium isopropoxide Cluster compounds Titanium Chemistry Size dependent Full Papers 021001 nanoscience & nanotechnology 0104 chemical sciences 3. Good health Methacrylic acid Physical chemistry 0210 nano-technology |
| Zdroj: | European Journal of Inorganic Chemistry |
| ISSN: | 1099-0682 1434-1948 |
| DOI: | 10.1002/ejic.201402670 |
| Popis: | The mixed-metal oxo clusters LnTi4O3(OiPr)2(OMc)11 (Ln = La, Ce; OMc = methacrylate), Ln2Ti6O6(OMc)18(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln2Ti4O4(OMc)14(HOMc)2 (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion. |
| Databáze: | OpenAIRE |
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