Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

Autor:	Hidekazu Kano, Toshihiro Kondo, Kohei Uosaki, Satoru Takakusagi, Kenji Hara, Shinobu Tayama, Masaya Sawamura, Takuya Masuda
Rok vydání:	2008
Předmět:	Silicon Surface Properties chemistry.chemical_element Catalysis Polymer chemistry Materials Chemistry Organometallic Compounds Organic chemistry Molecule Oxazoles Benzyl Alcohols Molecular Structure Metals and Alloys Oxidation reduction General Chemistry Ketones Recyclable catalyst Surfaces Coatings and Films Electronic Optical and Magnetic Materials Turnover number Oxygen chemistry Ceramics and Composites Surface modification Layer (electronics) Oxidation-Reduction Palladium
Zdroj:	Chemical communications (Cambridge, England). (41)
ISSN:	1359-7345
Popis:	A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::82473f60532c346036d2490aeff4e44f https://pubmed.ncbi.nlm.nih.gov/18217605 Zobrazit plný text záznamu