Stabilizing Low-Coordinated O Ions To Operate Cationic and Anionic Redox Chemistry of Li-Ion Battery Materials

Autor:	Keyi Chen, Zuosheng Li, Wenqing Zhang, Chilin Li, Jianjun Liu, Wujie Qiu
Rok vydání:	2019
Předmět:	Battery (electricity) Materials science Inorganic chemistry Cationic polymerization 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Redox 0104 chemical sciences Ion General Materials Science 0210 nano-technology
Zdroj:	ACS Applied Materials & Interfaces. 11:37768-37778
ISSN:	1944-8252 1944-8244
DOI:	10.1021/acsami.9b13463
Popis:	Conventional electrochemical processes are mainly operated by cationic redox chemistry. Developing cumulative cationic and anionic redox chemistry offers a transformative approach to increase the energy storage capacity of Li-ion batteries and active sites of catalysts. However, realizing the reversible anionic redox reaction to increase the specific capacity in Li-ion battery materials is a large challenge because uncontrollable anion-anion combination and gas evolutions cause poor cyclic performance. Here, we use open-framework metal-fluorides (FeF
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::820e20dd7fedd6e0ea123281198a8411 https://doi.org/10.1021/acsami.9b13463 Zobrazit plný text záznamu