Effect of Counterions on Properties of Micelles Formed by Alkylpyridinium Surfactants. 1. Conductometry and 1H-NMR Chemical Shifts
| Autor: | Jan B. F. N. Engberts, K Bijma |
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| Přispěvatelé: | Faculty of Science and Engineering, Stratingh Institute of Chemistry, Synthetic Organic Chemistry |
| Rok vydání: | 1997 |
| Předmět: |
ROD TRANSITION
inorganic chemicals Conductometry Inorganic chemistry Substituent SALTS MICELLIZATION Micelle chemistry.chemical_compound THERMODYNAMICS BINDING Electrochemistry General Materials Science SODIUM DODECYL-SULFATE Spectroscopy chemistry.chemical_classification Aqueous solution Chemical shift VISCOELASTICITY HALIDE SURFACTANTS Surfaces and Interfaces BROMIDE Condensed Matter Physics Crystallography chemistry Critical micelle concentration Pyridinium Counterion |
| Zdroj: | Langmuir, 13(18), 4843-4849. AMER CHEMICAL SOC |
| ISSN: | 1520-5827 0743-7463 |
| DOI: | 10.1021/la970171q |
| Popis: | This paper delineates the influence of counterions on the aggregation behavior of 1-methyl-4-n-dodecylpyridinium surfactants, using conductometry and H-1-NMR spectroscopy. Three types of counterions have been studied: (i) halides, (ii) alkanesulfonates, and (iii) aromatic counterions. The critical. micelle concentration is found to decrease with increasing counterion size and increasing counterion hydrophobicity, whereas the degree of counterion binding increases. The aggregation behavior of 1-methyl-4-n-dodecylpyridinium surfactants with aromatic counterions is shown to be markedly dependent on the substituent (hydrophobicity) and the substitution pattern in the aromatic ring of the counterion. Depending on the molecular architecture of the aromatic counterion, extremely long wormlike micelles can be formed instead of(nearly) spherical micelles. NMR experiments revealed that all aromatic counterions intercalate in between the pyridinium headgroups of the micelles, with more or less the same degree of penetration. All results can be explained on the basis of counterion-surfactant and counterion-water interactions, taking into account the specific microenvironment in the Stern layer. |
| Databáze: | OpenAIRE |
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