First syntheses of model long-chain trichloro[ω-(trimethylsilyl)alkynyl]silanes suitable for self-assembled monolayers on silicon surfaces
| Autor: | Anne-Sophie Castanet, Jean-François Bardeau, Estelle Banaszak, Li-Wen Xu, Jacques Mortier |
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| Přispěvatelé: | Unité de chimie organique moléculaire et macromoléculaire (UCO2M), Le Mans Université (UM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Laboratoire de physique de l'état condensé (LPEC), Centre National de la Recherche Scientifique (CNRS)-Le Mans Université (UM), Institut des Molécules et Matériaux du Mans (IMMM), Le Mans Université (UM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2009 |
| Předmět: |
Silicon
Trimethylsilyl [SDV]Life Sciences [q-bio] chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Chemical synthesis chemistry.chemical_compound Drug Discovery Polymer chemistry Monolayer [CHIM]Chemical Sciences Organic chemistry ComputingMilieux_MISCELLANEOUS Alkyl chemistry.chemical_classification Silanes [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Organic Chemistry self-assembled monolayers trichloro ω-alkynylsilanes Chemical modification Self-assembled monolayer 0104 chemical sciences chemistry |
| Zdroj: | Tetrahedron Tetrahedron, Elsevier, 2009, pp.3961-3966 Tetrahedron, Elsevier, 2009, 65 (20), pp.3961-3966. ⟨10.1016/j.tet.2009.03.046⟩ |
| ISSN: | 0040-4020 |
| Popis: | The preparation of the title compounds involves the introduction of the required Me 3 SiC C and trichlorosilyl groups at the termini of the alkyl chain via derivatization of easily accessible and inexpensive materials/reagents. Trichloro[ω-(trimethylsilyl)alkynyl]silanes are useful for the linkage to a hydroxylated silicon surface for multilayer formation and for further chemical modification of the tail group of the monolayer. |
| Databáze: | OpenAIRE |
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