Ester Transfer Reaction of Aromatic Esters with Haloarenes and Arenols by a Nickel Catalyst
| Autor: | Junichiro Yamaguchi, Kei Muto, Ryota Isshiki, Naomi Inayama |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Aryl food and beverages Halide chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Functional group Phenol derivative Organic chemistry Nickel catalyst Palladium |
| DOI: | 10.26434/chemrxiv.11577816.v1 |
| Popis: | A catalytic ester transfer reaction of aromatic esters with aryl halides/arenols was developed. The present reaction can transfer an ester functional group from certain aromatic esters to haloarenes. This ester transfer reaction involves two oxidative additions— one from the C–C bond of the aromatic ester and one from the C–halogen bond of haloarenes— onto a nickel catalyst. The utilization of a Ni/dcypt catalyst capable of cleaving both chemical bonds was a key for the reaction progress. Furthermore, naphthol-based aryl electrophiles were also applicable to the catalytic system via C–O bond activation. |
| Databáze: | OpenAIRE |
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