Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles

Autor: Giampaolo Manzolini, Paolo Iora, Costante Mario Invernizzi, Abubakr Ayub, Gioele Di Marcoberardino
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Control and Optimization
Materials science
Transcritical cycles
Fluid mixtures
020209 energy
Energy Engineering and Power Technology
Thermodynamics
Carbon dioxide
Organic rankine cycles
Waste heat recovery
02 engineering and technology
lcsh:Technology
7. Clean energy
Waste heat recovery unit
transcritical cycles
waste heat recovery
fluid mixtures
carbon dioxide
Organic Rankine Cycles
020401 chemical engineering
Heat recovery ventilation
Thermodynamic cycle
Waste heat
0202 electrical engineering
electronic engineering
information engineering

0204 chemical engineering
Electrical and Electronic Engineering
Engineering (miscellaneous)
Physics::Atmospheric and Oceanic Physics
Degree Rankine
Supercritical carbon dioxide
lcsh:T
Renewable Energy
Sustainability and the Environment

Supercritical fluid
13. Climate action
Working fluid
Energy (miscellaneous)
Zdroj: Energies; Volume 13; Issue 15; Pages: 4014
Energies, Vol 13, Iss 4014, p 4014 (2020)
ISSN: 1996-1073
DOI: 10.3390/en13154014
Popis: This study aims to provide a thermodynamic comparison between supercritical CO2 cycles and ORC cycles utilizing flue gases as waste heat source. Moreover, the possibility of using CO2 mixtures as working fluids in transcritical cycles to enhance the performance of the thermodynamic cycle is explored. ORCs operating with pure working fluids show higher cyclic thermal and total efficiencies compared to supercritical CO2 cycles; thus, they represent a better option for high-temperature waste heat recovery provided that the thermal stability at a higher temperature has been assessed. Based on the improved global thermodynamic performance and good thermal stability of R134a, CO2-R134a is investigated as an illustrative, promising working fluid mixture for transcritical power cycles. The results show that a total efficiency of 0.1476 is obtained for the CO2-R134a mixture (0.3 mole fraction of R134a) at a maximum cycle pressure of 200 bars, which is 15.86% higher than the supercritical carbon dioxide cycle efficiency of 0.1274, obtained at the comparatively high maximum pressure of 300 bars. Steam cycles, owing to their larger number of required turbine stages and lower power output, did not prove to be a suitable option in this application.
Databáze: OpenAIRE