A theory for the magnetic hyperfine interactions in the microwave spectrum of NO-HF
| Autor: | Brian J. Howard, C. R. Dennis, C. J. Whitham |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2001 |
| Předmět: |
Hydrogen
Magnetic moment Intermolecular force General Physics and Astronomy chemistry.chemical_element Diatomic molecule Dipole symbols.namesake chemistry symbols Physics::Atomic Physics Physics::Chemical Physics Physical and Theoretical Chemistry Atomic physics Hamiltonian (quantum mechanics) Open shell Hyperfine structure |
| Zdroj: | JOURNAL OF CHEMICAL PHYSICS. 115(3) |
| ISSN: | 0021-9606 |
| Popis: | A theory is presented for the fine and hyperfine interactions in the 2Π state open shell complexes like NO–HF containing remote magnetic nuclei. The nitrogen hyperfine Hamiltonian is based on the conventional Frosch and Foley treatment for diatomic radicals. An alternative treatment has been developed for the intermolecular hydrogen and fluorine magnetic hyperfine interactions based on a dipolar model for both electron spin and orbital magnetic moments. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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