Stable suprachannels via a columnar cyclodimeric ensemble: exchange and matrix of various liquid guests in SCSC fashion

Autor:	Lingling Yang, Ok-Sang Jung, Soomin Hyun, Dongwon Kim
Rok vydání:	2019
Předmět:	Denticity Materials science 010405 organic chemistry Molecular array 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Matrix (mathematics) Crystallography Adsorption Desorption Molecule Desolvation
Zdroj:	Dalton Transactions. 48:10927-10932
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c9dt00572b
Popis:	Self-assembly of ZnI2 with di(isoquinolin-5-yl)isophthalate (L) as a new bidentate N-donor gives rise to discrete crown-shaped M2L2 cyclodimers, 3.5CH3CN·0.7THF@[Zn2I4L2]. These metallacyclodimers are composed of a characteristically eclipsed molecular array, resulting in the formation of unusual 10.0 × 15.1 A2 diameter suprachannels. The suprachannels adsorb/desorb various liquid molecules in a rigid manner, which enables scientists to solve the structures of various liquids. This columnar molecular ensemble is an efficient, tolerant, and reproducible suprachannel matrix for structural determination of general liquid compounds via easy single-crystal-to-single-crystal (SCSC) guest exchange without any desolvation process.
Databáze:	OpenAIRE
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