Deep UV photochemistry of chemisorbed monolayers: patterned coplanar molecular assemblies

Autor: Charles S. Dulcey, J. H. Georger, Thomas L. Fare, David A. Stenger, Jeffrey M. Calvert, Victor Krauthamer
Rok vydání: 1991
Předmět:
Zdroj: Science (New York, N.Y.). 252(5005)
ISSN: 0036-8075
Popis: Deep ultraviolet (UV) irradiation is shown to modify organosilane self-assembled monolayer (SAM) films by a photocleavage mechanism, which renders the surface amenable to further SAM modification. Patterned UV exposure creates alternating regions of intact SAM film and hydrophilic, reactive sites. The exposed regions can undergo a second chemisorption reaction to produce an assembly of SAMs in the same molecular plane with similar substrate attachment chemistry. The UV-patterned films are used as a template for selective buildup of fluorophores, metals, and biological cells.
Databáze: OpenAIRE