Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions
| Autor: | Bo Wu, Yong-Gui Zhou, Han Wang, Changbin Yu, Xiang Li, Zi-Biao Zhao, Mu-Wang Chen |
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| Rok vydání: | 2020 |
| Předmět: |
Aryl
Asymmetric hydrogenation Metals and Alloys chemistry.chemical_element General Chemistry Combinatorial chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Kinetic resolution chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Palladium |
| Zdroj: | Chemical Communications. 56:5815-5818 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc00480d |
| Popis: | The first efficient palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones has been described through dynamic kinetic resolution under acidic conditions, providing a facile access to chiral trans cycloalkanol derivatives with excellent enantioselectivities. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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