Electro-osmotic flow of electrolyte solutions of PEO in microfluidic channels
Autor: | Pantelis Moschopoulos, Yannis Dimakopoulos, John Tsamopoulos |
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Rok vydání: | 2020 |
Předmět: |
Microchannel
Materials science Electro-osmosis Ionic bonding 02 engineering and technology Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Stress (mechanics) Colloid and Surface Chemistry Chemical engineering Rheology Soft matter 0210 nano-technology Microscale chemistry |
Zdroj: | Journal of Colloid and Interface Science. 563:381-393 |
ISSN: | 0021-9797 |
DOI: | 10.1016/j.jcis.2019.12.052 |
Popis: | Hypothesis We investigate if the shear-stress exerted on the wall of a glass microchannel can be a robust and accurate criterion for the safe electro-osmotic transfer of polyethylene oxide (PEO) chains dissolved in a NaCl aquatic solvent. To this end, a comprehensive multiscale formulation based on the rheological and electrochemical modeling of the PEO dynamics is proposed. Phenomena that occur in microscale, e.g., the migration of PEO to the core region of the channel and Polymeric Depletion Layer (PDL) formation, and in nanoscale, e.g., the development of an electric double layer on the glass surface and ionic steric effects, are included. Experimental arrangement We study the electro-osmotic flow of PEO solutions (0.1–0.5%), flowing in a glass microchannel of rectangle shape, with dimensions of 300 μm in length and 75 μm in height. We vary the externally applied electric field (300–500 V/cm), and the bulk ionic concentration (0.001–10 mM). Findings We find that all features of our formulation are indeed essential to reproduce the experimental data of Huang, Chen, Wong, Liow, Soft Matter, (2016) precisely. Although the PDL formation preserves the fragile nature of biopolymers, the dominant stress is the normal stress, and the critical value is at the PDL interface. A new design criterion for microdevices is proposed. |
Databáze: | OpenAIRE |
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