Synthesis, Surface Properties and Biological Activity of Long Chain Ammonium Herbicidal Ionic Liquids
| Autor: | Marta Fryder, Katarzyna Marcinkowska, Rafał Giszter, Agata Sznajdrowska |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Alternative methods
010405 organic chemistry wettability Biological activity General Chemistry 010402 general chemistry 01 natural sciences MCPA 0104 chemical sciences chemistry.chemical_compound chemistry herbicidal ionic liquids Ionic liquid Organic chemistry Thermal stability Ammonium Wetting herbicidal activity Long chain |
| Zdroj: | Journal of the Brazilian Chemical Society v.27 n.10 2016 Journal of the Brazilian Chemical Society Sociedade Brasileira de Química (SBQ) instacron:SBQ Journal of the Brazilian Chemical Society, Volume: 27, Issue: 10, Pages: 1774-1781, Published: OCT 2016 |
| ISSN: | 0103-5053 |
| DOI: | 10.5935/0103-5053.20160058 |
| Popis: | Herbicidal ionic liquids exhibit many advantages compared to conventional chemical plant protection agents, which allow for a reduction of the herbicide dose per hectare and decrease of toxicity. Popular herbicides, such as 4-chloro-2-methylphenoxyacetic (MCPA) or 2,4-dichlorophenoxyacetic (2,4-D) acids, can be modified by reaction with long chain ammonium cations in order to obtain novel forms. The aim of this study was to present an alternative method for the synthesis of herbicidal ionic liquids based on a natural cation known as Ethoquad C/12 and to analyze the physicochemical properties and herbicidal activity of the obtained products. New ionic liquids comprising MCPA and 2,4-D as anions were obtained and their chemical as well as thermal stability were evaluated. Furthermore, their biological and surface activity were investigated. The obtained results confirmed that the herbicidal activity has been preserved. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|