Reactions of Primary Amines with Tetracyanoethylene

Autor:	Yu. A. Kurskii, S. Ya. Khorshev, George A. Domrachev, E. Yu. Ladilina, Victor V. Semenov
Rok vydání:	2005
Předmět:	chemistry.chemical_compound Addition reaction Primary (chemistry) Chemistry Group (periodic table) Organic Chemistry Organic chemistry General Medicine Cyclohexylamine Tetracyanoethylene Acetonitrile Medicinal chemistry Single isomer
Zdroj:	ChemInform. 36
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200515062
Popis:	Primary amines, 3-triethoxysilylpropylamine, 3-silatranylpropylamine, and cyclohexylamine, react with tetracyanoethylene in acetonitrile at room temperature via addition at the cyano group to afford the corresponding amidines. N-Cyclohexyltricyanoacrylamidine exists as a mixture of two of the three possible isomers, while N-(3-triethoxysilylpropyl)tricyanoacrylamidine and N-(3-silatranylpropyl)tricyanoacrylamidine exist mainly as a single isomer containing NH2 group. N-(3-Triethoxysilylpropyl)tricyanoacrylamidine was used to prepare gels and films.
Databáze:	OpenAIRE
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