Gas promotes the crystallization of nano-sized metal–organic frameworks in ionic liquid
| Autor: | Buxing Han, X.L. Ma, Jianling Zhang, Cheng-Cheng Liu, Li Peng, Xinxin Sang, Xinchen Kang, Tianbin Wu, Bingxing Zhang |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Inorganic chemistry Metals and Alloys Cyclohexene Nanoparticle chemistry.chemical_element General Chemistry Oxygen Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention chemistry.chemical_compound chemistry law Ionic liquid Materials Chemistry Ceramics and Composites Metal-organic framework Crystallization Porosity |
| Zdroj: | Chemical Communications. 51:11445-11448 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Herein it was found that gas can be utilized as an activator to promote metal-organic framework (MOF) crystallization in IL at room temperature. The ultra-small MOF nanoparticles were obtained, and their size and porosity properties can be easily modulated by controlling gas pressure. The as-synthesized nano-sized Cu-MOF is an excellent candidate catalyst for the solvent-free oxidation of cyclohexene with oxygen. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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