cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis
| Autor: | Kacey G. Ortiz, David C. Powers, Cody J. Chalker, Hye Jeong Park, Ashley D. Cardenal |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Redox Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Hydroxylation chemistry.chemical_compound Decalin chemistry Materials Chemistry Ceramics and Composites Organic chemistry Porous medium |
| Zdroj: | Chemical Communications. 53:7377-7380 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Development of catalyst-controlled C-H hydroxylation could provide direct access to valuable synthetic targets, such as primary metabolites. Here, we report a new family of porous materials, comprised of 2-dimensional metalloporphyrin layers and flexible aliphatic linkers, and demonstrate C-H hydroxylation activity. We demonstrate that the stereochemistry of cis-decalin oxidation provides a useful tool for differentiating catalysis in from catalysis on porous materials, which is critical to leveraging the potential of porous materials for catalyst-controlled oxidation chemistry. |
| Databáze: | OpenAIRE |
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