Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines

Autor:	Eric S. Wiedner, Aaron M. Appel, Simone Raugei, Wendy J. Shaw, R. Morris Bullock
Rok vydání:	2022
Předmět:	Hydrogenase General Chemistry Amines Ligands Catalysis Hydrogen
Zdroj:	Chemical Reviews. 122:12427-12474
ISSN:	1520-6890 0009-2665
Popis:	Pendant amines play an invaluable role in chemical reactivity, especially for molecular catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which contain a pendant amine positioned for cooperative bifunctionality, synthetic catalysts have been developed to emulate this multifunctionality through incorporation of a pendant amine in the second coordination sphere. Cyclic diphosphine ligands containing two amines serve as the basis for a class of catalysts that have been extensively studied and used to demonstrate the impact of a pendant base. These 1,5-diaza-3,7-diphosphacyclooctanes, now often referred to as "P
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f7cec8d1f907d13cc091b59fe881c9a https://doi.org/10.1021/acs.chemrev.1c01001 Zobrazit plný text záznamu