Direct formation of an organonitrogen compound from a molybdenum nitrido species
| Autor: | Alexander Volker Peters, Huub J.W. Henderickx, Koen de Vries, Jan Van Der Spoel, G.T.C. Kwakkenbos |
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| Rok vydání: | 2003 |
| Předmět: |
Inorganic chemistry
Metals and Alloys chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Molybdenum Yield (chemistry) Reagent Materials Chemistry Ceramics and Composites Trifluoroacetic acid |
| Zdroj: | Chemical Communications. :2050 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/b305774g |
| Popis: | The molybdenum nitrido complex 15NMo[N(R)Ar]3 (where R = C(CD3)2CH3, Ar = 3,5-C6H3Me2) reacted with the anhydride of trifluoroacetic acid at room temperature to afford the correspondent organonitrogen compound in almost quantitative yield without the necessity of using additional reagents to achieve the C–N coupling. |
| Databáze: | OpenAIRE |
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