Réaction compétitive de la substitution homolytique intramoléculaire : décomposition de pero×ydes allyliques dans le thioglycolate de méthyle

Autor:	Evelyne Montaudon, M. J. Bourgeois, Marianne Vialemaringe, Monique Campagnole
Rok vydání:	2001
Předmět:	Allylic rearrangement organic chemicals Organic Chemistry food and beverages Epoxide General Chemistry Medicinal chemistry Peroxide Decomposition Catalysis Adduct Methyl thioglycolate Homolysis chemistry.chemical_compound chemistry Intramolecular force Organic chemistry
Zdroj:	Canadian Journal of Chemistry. 79:257-262
ISSN:	1480-3291 0008-4042
Popis:	The decomposition of allylic peroxides in methyl thioglycolate always leads to both epoxide and adduct peroxide. According to the nature of the allylic chain, either epoxide or peroxide is the predominant product, if not the only one. It is the first example where the hydrogen transfer is as fast as the intramolecular homolytic substitution. The influence of different factors upon the competition is studied.Key words: allylic peroxides, epoxides, intramolecular homolytic substitution, transfer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f08db1c933ec06f7727ba8e83e920d7 https://doi.org/10.1139/cjc-79-3-257 Zobrazit plný text záznamu Plný text ve formátu PDF