A Six-Bowl Carceplex That Entraps Seven Guest Molecules
| Autor: | John C. Sherman, Darren A. Makeiff and |
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| Rok vydání: | 2005 |
| Předmět: |
Models
Molecular Macrocyclic Compounds Aqueous solution Chemistry Stereochemistry Shell (structure) Water Dimethylformamide Resorcinols General Chemistry Biochemistry Solution structure Catalysis Inclusion compound chemistry.chemical_compound Colloid and Surface Chemistry Ethers Cyclic Spectrometry Mass Matrix-Assisted Laser Desorption-Ionization Acetamides Polymer chemistry Molecule Dimethyl Sulfoxide Selectivity |
| Zdroj: | Journal of the American Chemical Society. 127:12363-12367 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja0520621 |
| Popis: | A six-bowl carceplex that entraps seven guest molecules, 5.(DMSO)7, was synthesized and characterized. The dynamics of the host shell was studied in solution in the absence and presence of water. A multiple-molecule template was found to drive the formation of 5.(DMSO)x.G(7-x) (G = DMA, DMF; x = 5-7). Higher selectivity was found for species containing greater numbers of DMSO molecules. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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