Metal-ligand cooperation at tethered π-ligands
| Autor: | Verhoeven, Dide G. A., Moret, Marc-Etienne, Sub Organic Chemistry and Catalysis, Organic Chemistry and Catalysis |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Double bond 010405 organic chemistry Stereochemistry Ligand Cooperativity Homogeneous catalysis 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry Metal chemistry visual_art Metal–ligand multiple bond visual_art.visual_art_medium Reactivity (chemistry) |
| Zdroj: | Dalton Transactions, 45(40), 15762. Royal Society of Chemistry |
| ISSN: | 1477-9234 1477-9226 |
| Popis: | Metal-ligand cooperativity in homogeneous catalysis is emerging as a powerful tool for the design of efficient transition-metal catalysts. This perspective highlights recent advances in the use of neutral π-coordinating ligands, tethered to a transition-metal center by other donor ligands, as cooperative reaction centers. The state-of-the-art organometallic complexes, including π-coordinating ligands originating from C[double bond, length as m-dash]C, C[double bond, length as m-dash]E (E = O, N) and boron containing moieties, are described here, with special attention on their specific reactivity. Geometric and electronic aspects of ligand design and their influence on the coordination mode and reactivity of the π-system are discussed. |
| Databáze: | OpenAIRE |
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