Hydrogenation of graphene by reaction at high pressure and high temperature
| Autor: | Dean Smith, Christopher A. Muryn, Konstantin S. Novoselov, John E. Proctor, Ross T. Howie, Eugene Gregoryanz, Yong-Jin Kim, Matthew P. Halsall, Iain F. Crowe, Vladimir Vishnyakov, Cristina L. Simionescu |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Materials science
Hydrogen Graphene Graphene foam General Engineering General Physics and Astronomy chemistry.chemical_element Diamond Nanotechnology engineering.material Diamond anvil cell law.invention chemistry.chemical_compound chemistry Chemical engineering law engineering Graphane General Materials Science Graphene nanoribbons graphene functionalized graphene hydrogenated graphene graphane diamond anvil cell Graphene oxide paper |
| Zdroj: | Smith, D, Howie, R T, Crowe, I F, Simionescu, C L, Muryn, C, Vishnyakov, V, Novoselov, K S, Kim, Y-J, Halsall, M P, Gregoryanz, E & Proctor, J E 2015, ' Hydrogenation of Graphene by Reaction at High Pressure and High Temperature ', ACS Nano, vol. 9, no. 8, pp. 8279-8283 . https://doi.org/10.1021/acsnano.5b02712 |
| ISSN: | 1936-0851 |
| DOI: | 10.1021/acsnano.5b02712 |
| Popis: | The chemical reaction between hydrogen and purely sp2-bonded graphene to form grapheneâÂÂs purely sp3-bonded analogue, graphane, potentially allows the synthesis of a much wider variety of novel two-dimensional materials by opening a pathway to the application of conventional chemistry methods in graphene. Graphene is currently hydrogenated by exposure to atomic hydrogen in a vacuum, but these methods have not yielded a complete conversion of graphene to graphane, even with graphene exposed to hydrogen on both sides of the lattice. By heating graphene in molecular hydrogen under compression to modest high pressure in a diamond anvil cell (2.6 â 5.0 GPa), we are able to react graphene with hydrogen and propose a method whereby fully-hydrogenated graphane may be synthesized for the first time. |
| Databáze: | OpenAIRE |
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