Theoretical model of adsorption in a templated porous material

Autor:	Van Tassel Pr
Rok vydání:	1999
Předmět:	Adsorption Materials science Component (thermodynamics) Non-equilibrium thermodynamics Binary number Thermodynamics Physical chemistry Statistical mechanics Selectivity Porosity
Zdroj:	Physical Review E. 60:R25-R28
ISSN:	1095-3787 1063-651X
Popis:	We introduce a theoretical description of adsorption in a templated porous material modeled as a quenched binary mixture configuration with one component removed. Using tools from equilibrium statistical mechanics, we analyze the diagrammatic structure of and derive an approximate formula for this nonequilibrium material's porosity and Henry regime selectivity. We find that templating significantly increases the porosity as well as the selectivity for the larger component of a mixture.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7eaab8286f9870e333ad45a9760d16d5 https://doi.org/10.1103/physreve.60.r25 Zobrazit plný text záznamu