HYPERBRANCHED POLYGLYCEROLS WITH BISPHENOL A CORE AS GLYCEROL-DERIVED COMPONENTS OF POLYURETHANE WOOD ADHESIVES
| Autor: | Andrzej Antczak, M Maminski, Karolina Szymona, Rafał Szymański, Paweł G. Parzuchowski |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
Glycerol
Hyperbranched polyglycerols Polyurethane Bisphenol A Environmental Engineering Materials science lcsh:Biotechnology Substrate (chemistry) Bioengineering Core (manufacturing) Solid wood Isocyanate chemistry.chemical_compound chemistry Chemical engineering lcsh:TP248.13-248.65 Adhesives for wood Organic chemistry Adhesive Waste Management and Disposal |
| Zdroj: | BioResources, Vol 7, Iss 2, Pp 1440-1451 (2012) |
| ISSN: | 1930-2126 |
| DOI: | 10.15376/biores.7.2.1440-1451 |
| Popis: | Two hyperbranched polyglycerols (HBPGs) and one oligoglycerol containing bisphenol A in the core of the molecule were synthesized from glycerol carbonate and applied as polyols in 2-component polyurethane adhesive systems. It was shown that mechanical performance of the joints made in solid wood depended on the hydroxyl functionality of the polyglycerol as well as on the type of the isocyanate used as a cross-linker. The shear strengths of the best-performing joints exceeded that of the substrate. Eventually, it was proved that hyperbranched polyglycerols might be convenient glycerol-derived raw materials for polyurethane adhesives. |
| Databáze: | OpenAIRE |
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