Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides
| Autor: | Daiki Kuroda, Takuya Kurahashi, Toshifumi Takahashi, Seijiro Matsubara, Yuji Yoshida, Toru Kuwano |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Aryl Intermolecular force Metals and Alloys Alkyne chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis Reductive elimination 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Nickel Materials Chemistry Ceramics and Composites |
| Zdroj: | Chemical communications (Cambridge, England). 54(90) |
| ISSN: | 1364-548X |
| Popis: | Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed. The reaction involves radical-mediated formal alkyne insertion into the carbon-nickel bond and carbon-iodine reductive elimination facilitated by Ni(iii) species. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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