Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse
| Autor: | Ephrath Solel, Ehud Keinan, Pravat Mondal, Ofer Reany, Shubhanjan Mitra |
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| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Organic Chemistry technology industry and agriculture chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Sulfur 0104 chemical sciences symbols.namesake chemistry Chemical physics Intramolecular force symbols Physical and Theoretical Chemistry van der Waals force human activities |
| Zdroj: | Organic letters. 22(1) |
| ISSN: | 1523-7052 |
| Popis: | This study confirms the hypothesis that bambusurils (BUs) with equatorial sulfur atoms cannot assume an anion-binding jigger conformation due to strong intramolecular van der Waals attractive interactions. NMR, X-ray crystallography, and computation with newly synthesized |
| Databáze: | OpenAIRE |
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