Experimental densities, dynamic viscosities and surface tensions of the ionic liquids series 1-ethyl-3-methylimidazolium acetate and dicyanamide and their binary and ternary mixtures with water and ethanol at T=(298.15 to 343.15K)

Autor:	S. van der Boogaart, J.H. Lijbers, E. Quijada-Maldonado, G.W. Meindersma, A.B. de Haan
Rok vydání:	2012
Předmět:	Aqueous solution Atmospheric pressure Chemistry Thermodynamics Atmospheric temperature range Atomic and Molecular Physics and Optics Surface tension chemistry.chemical_compound Ionic liquid Polar General Materials Science Physical and Theoretical Chemistry Ternary operation Dicyanamide
Zdroj:	The Journal of Chemical Thermodynamics, 51, 51-58. Academic Press Inc.
ISSN:	0021-9614
DOI:	10.1016/j.jct.2012.02.027
Popis:	In this paper, experimental densities and dynamic viscosities of 1-ethyl-3-methylimidazolium based ionic liquids (ILs) with the anions acetate and dicyanamide are presented in a wide temperature range (298.15 to 343.15 K) at atmospheric pressure. Surface tension of these ILs was measured at T = 298.15 K. The effect of water and/or ethanol compositions on densities and dynamic viscosities of these ILs are studied in binary and ternary mixtures. A quadratic mixing rule was used to correlate binary and ternary liquid densities. The Eyring–Patel–Teja model, which is recommended for polar and aqueous systems, is used to correlate dynamic viscosity data over the whole range of compositions and temperatures in binary and ternary mixtures. Temperature-dependent interaction parameters are introduced here to account for the changes of viscosities with temperature showing good agreements with experimental data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d8af72b78065bf3d7bc60426d3841c2 https://doi.org/10.1016/j.jct.2012.02.027 Zobrazit plný text záznamu Full Text from ScienceDirect