Electroless deposition of Fe-Ni alloys from acidic and alkaline solutions using hypophosphite as a reducing agent
| Autor: | Thomas Thundat, Željka Antić, Nada Djokić, Stojan S. Djokić |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Reducing agent Hypophosphite Phosphorus Inorganic chemistry technology industry and agriculture chemistry.chemical_element mechanism General Chemistry 010402 general chemistry equipment and supplies 01 natural sciences 0104 chemical sciences Amorphous solid Ion Autocatalysis lcsh:Chemistry chemistry.chemical_compound Hydrolysis chemistry hydrolysis lcsh:QD1-999 chemical deposition Deposition (chemistry) |
| Zdroj: | Journal of the Serbian Chemical Society, Vol 84, Iss 11, Pp 1199-1208 (2019) Journal of the Serbian Chemical Society |
| ISSN: | 1820-7421 0352-5139 |
| Popis: | The deposition of Fe–Ni alloys from acidic and alkaline solutions, using hypophosphite as a reducing agent, is studied in this work. The experimental results confirm the autocatalytic nature of this process. The composition of alloys is practically independent of the temperature deposition. Fe–Ni alloys produced from acidic solutions contained less than 1% Fe. The amount of Fe in Fe–Ni alloys produced from alkaline solutions was estimated to be about 15 %. The deposition of Fe–Ni alloys was significantly faster in the alkaline than in the acidic solutions, due to more pronounced hydrolysis of Fe(II) and Ni(II) ions under the alkaline conditions. The Fe–Ni alloys produced from both acidic and alkaline solutions contain phosphorus and as such have amorphous structure. © 2019 Serbian Chemical Society. All rights reserved. |
| Databáze: | OpenAIRE |
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