Autor: |
Penafiel, Itziar, Martinez-Lombardia, A, Godard, C, Claver, Carmen, Lapkin, AA |
Přispěvatelé: |
Lapkin, Alexei [0000-0001-7621-0889], Apollo - University of Cambridge Repository |
Rok vydání: |
2019 |
Předmět: |
|
DOI: |
10.17863/cam.35134 |
Popis: |
A new family of well-defined NHC-Pd complexes immobilised onto silica, alumina and titania is reported. The catalysts display activity and recyclability in the Sonogashira cross-coupling reactions under batch and continuous flow conditions. Under batch conditions the new catalytic systems were recycled up to four times with yields over 80%. These catalysts have a broad substrate scope of different aryl bromides and alkynes. The titania-supported catalysts show good conversions under continuous flow conditions at least over 8 hours on stream using MeOH as solvent. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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