Reply to comment on 'aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes': origin of the enhanced phosphorescence

Autor:	Fuyou Li, Tao Yi, Chunhui Huang, Huazhou Wu, Mei Shi, Kewei Huang
Rok vydání:	2009
Předmět:	Materials science Metals and Alloys Solid-state Stacking chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography chemistry Intramolecular force Materials Chemistry Ceramics and Composites Iridium Phosphorescence
Zdroj:	Chemical communications (Cambridge, England). (10)
ISSN:	1359-7345
Popis:	An obvious enhanced phosphorescence emission in the solid state (EPESS) was observed for two iridium(III) complexes with restricted (even fixed) intramolecular rotational motion, which is contrary to the opinion ("restricted intramolecular rotational motion as the origin of EPESS") of Park et al., and our observation confirmed that the pi-pi stacking of adjacent pyridyl rings of ppy ligands played a key role in EPESS.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d3e5eb9e49b5e57c0efc1cc9e413b6c https://pubmed.ncbi.nlm.nih.gov/18758605 Zobrazit plný text záznamu