Determination of Benzo[]pyrene in smoking-flavour agents (water-soluble liquid smoke) by second derivative constant-wavelength synchronous spectrofluorimetry

Autor:	S. García Falcón, M.A. Lage Yusty, J. Simal Lozano, M.J. López de Alda Villaizán, S. González Amigo
Rok vydání:	1996
Předmět:	Smoke Chromatography food.ingredient Elution Fluorescence spectrometry Analytical Chemistry Hexane chemistry.chemical_compound Liquid smoke food Benzo(a)pyrene chemistry Pyrene Second derivative
Zdroj:	Talanta. 43:659-664
ISSN:	0039-9140
DOI:	10.1016/0039-9140(95)01811-5
Popis:	We have developed a simple, rapid, inexpensive method for the determination of benzo[a]pyrene (BP, a known carcinogen) in smoking-flavour agents (water-soluble liquid smoke; WSLS). After purification of the WSLS by a single passage through a Sep Pak C18 Plus cartridge, BP in the hexane eluate was determined by second derivative constant-wavelength synchronous spectrofluorimetry. Method precision (RSD6%) and recovery ( approximately 92%) were satisfactory, and the detection and quantification limits (1.05 and 2.28 mug kg(-1) respectively) indicated that the current maximum permissible concentration of BP in smoke flavourings (10 mug kg(-1)) can be monitored by this method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d3b82cb33aabf6bab6755c452cb6c6c https://doi.org/10.1016/0039-9140(95)01811-5 Zobrazit plný text záznamu Full Text from ScienceDirect