| Autor: |
Mariateresa Giustiniano, Rolando Cannalire, Gian Cesare Tron, Alfonso Carotenuto, Giulia Graziani, Federica Santoro, Diego Brancaccio, Camilla Russo |
| Přispěvatelé: |
Cannalire, Rolando, Santoro, Federica, Russo, Camilla, Graziani, Giulia, Cesare Tron, Gian, Carotenuto, Alfonso, Brancaccio, Diego, Giustiniano, Mariateresa |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
ACS Organic & Inorganic Au, Vol 2, Iss 1, Pp 66-74 (2021) |
| ISSN: |
2694-247X |
| DOI: |
10.1021/acsorginorgau.1c00028 |
| Popis: |
The merging of micellar and photoredox catalysis represents a key issue to promote “in water” photochemical transformations. A photomicellar catalyzed synthesis of amides from N-methyl-N-alkyl aromatic amines and both aliphatic and aromatic isocyanides is herein presented. The mild reaction conditions enabled a wide substrate scope and a good functional groups tolerance, as further shown in the late-stage functionalization of complex bioactive scaffolds. Furthermore, solution 1D and 2D NMR experiments performed, for the first time, in the presence of paramagnetic probes enabled the study of the reaction environment at the atomic level along with the localization of the photocatalyst with respect to the micelles, thus providing experimental data to drive the identification of optimum photocatalyst/surfactant pairing. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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