Inhibitory effect of fungoid chitosan in the generation of aldehydes relevant to photooxidative decay in a sulphite-free white wine

Autor: Mathieu Cassien, Claudio Riponi, Nicolas Vidal, Antonio Castro Marín, Fabio Chinnici, Sophie Thétiot-Laurent, Marcel Culcasi, Pierre Stocker, Sylvia Pietri, Bertrand Robillard
Přispěvatelé: Castro Marin, Antonio, Stocker, Pierre, Chinnici, Fabio, Cassien, Mathieu, Thétiot-Laurent, Sophie, Vidal, Nicola, Riponi, Claudio, Robillard, Bertrand, Culcasi, Marcel, Pietri, Sylvia, Institut de Chimie Radicalaire (ICR), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), University of Bologna, YELEN, Institut Oenologique de Champagne, ANR-17-CE34-0006,MITODIAPM,Sondes mitochondriales et dispositifs de génération d'aérosols pour l'étude du stress oxydant et des dysfonctionnements cardiométaboliques induits par l'inhalation de faibles niveaux de particules ultrafines de pesticides chez l'animal(2017), University of Bologna/Università di Bologna
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Food Chemistry
Food Chemistry, Elsevier, 2021, ⟨10.1016/j.foodchem.2021.129222⟩
Food Chemistry, 2021, ⟨10.1016/j.foodchem.2021.129222⟩
ISSN: 0308-8146
1873-7072
Popis: International audience; The reaction pathways were investigated by which a fungoid chitosan (CsG) may protect against photooxidative decay of model solutions and a sulphite-free white wine. Samples containing CsG were dark incubated for 2 days before exposure to fluorescent lighting for up to 21 days in the presence of wine like (+)-catechin and/or iron doses. In both systems CsG at winemaking doses significantly reduced the photoproduction of acetaldeyde and, to a better extent, glyoxylic acid, two key reactive aldehydes implicated in wine oxidative spoilage. After 21 dayx, CsG was two-fold more effective than sulfur dioxide in preventing glyoxylic acid formation and minimizing the browning of white wine. Among the antioxidant mechanisms involved in CsG protective effect, iron chelation, and hydrogen peroxide quenching were demonstrated. Besides, the previously unreported tartrate displacement from the (iron(III)-tartrate) complex was revealed as an additional inhibitory mechanism of CsG under photo-Fenton oxidation conditions.
Databáze: OpenAIRE