Diastereoselective Synthesis of Substituted Tetrahydropyrans by Copper(II)–Bisphosphine-Catalyzed Olefin Migration and Prins Cyclization

Autor:	Jorden Kass, Daniel R. Nicponski, Arun K. Ghosh, Chad Keyes
Jazyk:	angličtina
Rok vydání:	2012
Předmět:	chemistry.chemical_compound Olefin fiber Chemistry Organic Chemistry chemistry.chemical_element Tetrahydropyran Prins reaction Copper Combinatorial chemistry Catalysis Article
Popis:	We developed a copper(II) triflate-bisphosphine complex catalyzed olefin migration and Prins cyclization which lead to the synthesis of substituted tetrahydropyran derivatives. The protocol is convenient and a variety of substituted tetrahydropyrans were obtained in good to excellent yields with excellent diastereoselectivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c73c23447ed0f5c4864d32b715b406d https://europepmc.org/articles/PMC6237189/ Zobrazit plný text záznamu