In an ionic liquid, high local friction is determined by the proximity to the charge network
| Autor: | Juan C. Araque, Claudio J. Margulis |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Work (thermodynamics)
Materials science 010304 chemical physics General Physics and Astronomy Charge (physics) 010402 general chemistry 01 natural sciences Structural heterogeneity Methane 0104 chemical sciences Solvent Viscosity chemistry.chemical_compound chemistry Chemical physics 0103 physical sciences Ionic liquid Physical and Theoretical Chemistry Imide |
| Zdroj: | The Journal of Chemical Physics. 149:144503 |
| ISSN: | 1089-7690 0021-9606 |
| Popis: | Structural heterogeneity in Ionic Liquids (ILs) is to a large extent defined by nanoscale apolar pockets that act as spacers between strings of positive and negative charges that alternate. In contrast to this, recent work from our group and that of others appear to indicate that dynamic, energetic, and mechanical heterogeneities are governed by the charged part of the liquid. In this article, we study the dynamics of methane, a small apolar solute, in the family of ILs 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (Im1,n+/NTf2−), with n = 2, 4, 8 at temperatures that make the viscosity for each liquid similar and around 8 cP. We do this in an attempt to equalize the effect of the solvent on the dynamics of the solute. In all cases, we find that solute proximity to charge-enhanced regions coincides with translationally caged regimes (high local friction) whereas the opposite is true in charge-depleted regions. In a way, these ILs behave like a liquid within a liquid where the charge network is the high friction component.Structural heterogeneity in Ionic Liquids (ILs) is to a large extent defined by nanoscale apolar pockets that act as spacers between strings of positive and negative charges that alternate. In contrast to this, recent work from our group and that of others appear to indicate that dynamic, energetic, and mechanical heterogeneities are governed by the charged part of the liquid. In this article, we study the dynamics of methane, a small apolar solute, in the family of ILs 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (Im1,n+/NTf2−), with n = 2, 4, 8 at temperatures that make the viscosity for each liquid similar and around 8 cP. We do this in an attempt to equalize the effect of the solvent on the dynamics of the solute. In all cases, we find that solute proximity to charge-enhanced regions coincides with translationally caged regimes (high local friction) whereas the opposite is true in charge-depleted regions. In a way, these ILs behave like a liquid within a liquid where the charge networ... |
| Databáze: | OpenAIRE |
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