| Autor: |
Tobias Reich, Harald Funke, Christoph Hennig, Antje Gupta, Roger Alberto, Bernd Johannsen, Jens-Uwe Kunstler, A. Roßberg, H.-J. Pietzsch, Sepp Seifert |
| Jazyk: |
angličtina |
| Rok vydání: |
2000 |
| Předmět: |
|
| Zdroj: |
Radiochim. Acta 88 (2000) 239-245 |
| Popis: |
EXAFS analyses were successfully used to determine the structure of Re and Tc carbonyl thioether complexes in solid and liquid samples. In connection with chromatographic and mass spectrometric methods the behaviour of Tc carbonyl dithioether complexes in aqueous solution was studied. It was found that complexes containing a bidentate thioether ligand are able to react with water by exchange of the chloride ion, which results in the formation of a cationic complex. As expected, the exchange proceeds faster at the n.c.a. level because of concentration differences. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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