Tandem Functionalization‐Carboxylation Reactions of π‐Systems with CO 2

Autor:	Lorenzo Lombardi, Giulio Bertuzzi, Alessandro Cerveri, Marco Bandini
Přispěvatelé:	Bertuzzi, Giulio, Cerveri, Alessandro, Lombardi, Lorenzo, Bandini, Marco
Rok vydání:	2021
Předmět:	Carboxylation Tandem Cascade reaction Chemistry Tandem reaction Surface modification Double bond General Chemistry Carbon Dioxide Photocatalyisis Metal catalysis Combinatorial chemistry Catalysis
Zdroj:	Chinese Journal of Chemistry. 39:3116-3126
ISSN:	1614-7065 1001-604X
DOI:	10.1002/cjoc.202100450
Popis:	The tandem catalytic functionalization/carboxylation of double as well as triple carbon-carbon bonds with CO2 represent an emerging research area in synthetic organic methodology. In particular, the combination of mild reaction conditions, stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/ complexity from readily available unsaturated hydrocarbons and CO2 as a C1-buinding block. The most recent developments in the field have been collected in the present review article and organized, based on the different sets of π-systems/intermediates/reactive partners employed (i.e., nickelalactones, organo-halides) as well as synthetic strategies (i.e., visible-light photo redox catalysis).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c262ff1f5cf6472f33dd04277abcb35 https://doi.org/10.1002/cjoc.202100450 Zobrazit plný text záznamu Plný text