Rotamerism-driven large magnitude host–guest binding change in a crown ether derivatized pyridinium-phenolate series

Autor:	Ming Jin, Jean-Pierre Malval, Théophile Tschamber, Nelly Hobeika, Hélène Chaumeil, Emel Ay, Davy-Louis Versace
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Metals and Alloys 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry Potassium Cation 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Transduction (biophysics) chemistry.chemical_compound chemistry Nucleophile Materials Chemistry Ceramics and Composites Pyridinium 0210 nano-technology Crown ether Order of magnitude
Zdroj:	Chemical Communications. 52:4652-4654
ISSN:	1364-548X 1359-7345
Popis:	Two TICTOID-based pyridinium-phenolates bearing a crown ether macrocycle have been designed for the complexation of a potassium cation. The nucleophilicity of the intraannular phenolate -O(-) function can be strongly modulated by biaryl twisting. Such a structure/electronic transduction effect gives rise to a host-guest binding change by more than two orders of magnitude.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c25e131a8ae2e708085b5a7871c2f7a https://doi.org/10.1039/c6cc00684a Zobrazit plný text záznamu