Highly (Z)-selective synthesis of beta-monosubstituted alpha,beta-unsaturated cyanides using the peterson reaction

Autor:	Tomohide Fukuzaki, Yutaka Murai, Satoshi Kojima, and Atsushi Yamakawa
Rok vydání:	2004
Předmět:	Chemistry Stereochemistry Organic Chemistry Alpha (ethology) Physical and Theoretical Chemistry Selectivity Beta (finance) Biochemistry
Zdroj:	Organic letters. 6(22)
ISSN:	1523-7060
Popis:	[reaction: see text] The Peterson reaction between (t-BuO)Ph(2)SiCH(2)CN and various aldehydes furnishes the corresponding beta-monosubstituted alpha,beta-unsaturated cyanides with high Z selectivity (Z:E = 92:8 to98:2).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7bffa77d4d6f6773c57fbaccc9b46c06 https://pubmed.ncbi.nlm.nih.gov/15496063 Zobrazit plný text záznamu