Binary Lead Fluoride Pb3F8
| Autor: | H. Lars Deubner, Jan Herritsch, Benedikt P. Klein, Jörn Schmedt auf der Günne, Claudio K. Krug, Sergei I. Ivlev, J. Michael Gottfried, Jascha Bandemehr, Stefan R. Kachel, Maik Schöniger, Jamal N. M. Aman, Antti J. Karttunen, Lukas Ruppenthal, Malte Sachs, Florian Kraus |
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| Přispěvatelé: | University of Marburg, Department of Chemistry and Materials Science, University of Siegen, Aalto-yliopisto, Aalto University |
| Rok vydání: | 2019 |
| Předmět: |
lead fluoride
Thermogravimetric analysis Valence (chemistry) 010405 organic chemistry Chemistry Organic Chemistry General Chemistry Nuclear magnetic resonance spectroscopy 010402 general chemistry 01 natural sciences Catalysis XANES 0104 chemical sciences NEXAFS IR and Raman spectroscopy symbols.namesake NMR spectroscopy symbols Anhydrous Physical chemistry quantum chemical calculations Raman spectroscopy Electronic band structure Spectroscopy |
| Zdroj: | Chemistry – A European Journal. 25:15656-15661 |
| ISSN: | 1521-3765 0947-6539 |
| DOI: | 10.1002/chem.201903954 |
| Popis: | The binary lead fluoride Pb3F8 was synthesized by the reaction of anhydrous HF with Pb3O4 or by the reaction of BrF3 with PbF2. The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS 19F NMR spectroscopy, as well as thermogravimetric analysis, XP and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Solid-state quantum-chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound. |
| Databáze: | OpenAIRE |
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