New Directions in Metal Phosphonate and Phosphinate Chemistry
| Autor: | Ferdinando Costantino, Konstantinos D. Demadis, Sébastien Sallard, Maria Vassaki, Paul A. Wright, Norbert Stock, Aurelio Cabeza, Stephen J. I. Shearan, Riccardo Vivani, Jan Demel, Marco Taddei, Inés R. Salcedo, Franziska Emmerling |
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| Přispěvatelé: | University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Porous metal
synthesis Metal phosphonates and phosphinates General Chemical Engineering rechargeable batteries T-NDAS gas sorption/separation Nanotechnology Heterogenous catalysis Phosphinate 010402 general chemistry metal phosphonates and phosphinates 01 natural sciences Inorganic Chemistry Metal Synthesis chemistry.chemical_compound metal–organic frameworks proton conduction Layered materials Drug delivery Gas sorption/separation Heterogeneous catalysis In situ characterisation Metal–organic frameworks Proton conduction Rechargeable batteries X-ray and electron diffraction lcsh:QD901-999 QD General Materials Science 010405 organic chemistry QD Chemistry Condensed Matter Physics Phosphonate in situ characterisation 0104 chemical sciences heterogeneous catalysis chemistry layered materials visual_art drug delivery visual_art.visual_art_medium Fuel cells Metal-organic framework lcsh:Crystallography |
| Zdroj: | Crystals, Vol 9, Iss 5, p 270 (2019) |
| ISSN: | 2073-4352 |
| Popis: | M.T is supported by funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No 663830. In September 2018, the First European Workshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current research efforts and identifying future directions. The scope of this perspective article is to provide a critical overview of the topics discussed during the workshop, which are divided into two main areas: synthesis and characterisation, and applications. In terms of synthetic methods, there has been a push towards cleaner and more efficient approaches. This has led to the introduction of high-throughput synthesis and mechanochemical synthesis. The recent success of metal–organic frameworks has also promoted renewed interest in the synthesis of porous metal phosphonates and phosphinates. Regarding characterisation, the main advances are the development of electron diffraction as a tool for crystal structure determination and the deployment of in situ characterisation techniques, which have allowed for a better understanding of reaction pathways. In terms of applications, metal phosphonates have been found to be suitable materials for several purposes: they have been employed as heterogeneous catalysts for the synthesis of fine chemicals, as solid sorbents for gas separation, notably CO2 capture, as materials for electrochemical devices, such as fuel cells and rechargeable batteries, and as matrices for drug delivery. Publisher PDF |
| Databáze: | OpenAIRE |
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