Ultrasound-Enhanced Deracemization: Toward the Existence of Agonist Effects in the Interpretation of Spontaneous Symmetry Breaking
| Autor: | Gérard Coquerel, Jean-Christophe Plaquevent, Céline Rougeot, Frédéric Guillen |
|---|---|
| Přispěvatelé: | Synthèse et Physico-Chimie de Molécules d'Intérêt Biologique (SPCMIB), Institut de Chimie de Toulouse (ICT-FR 2599), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Sciences et Méthodes Séparatives (SMS), Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Normandie Université (NU), Propre |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Agonist
010405 organic chemistry medicine.drug_class Chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Spontaneous symmetry breaking General Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry [CHIM.THER]Chemical Sciences/Medicinal Chemistry 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Crystallography Chemical physics medicine [CHIM.CRIS]Chemical Sciences/Cristallography General Materials Science Entrainment (chronobiology) ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Crystal Growth & Design Crystal Growth & Design, American Chemical Society, 2015, 15 (5), pp.2151-2155. ⟨10.1021/cg501765g⟩ |
| ISSN: | 1528-7483 1528-7505 |
| DOI: | 10.1021/cg501765g⟩ |
| Popis: | Both isothermal attrition-enhanced and ultrasound-enhanced deracemizations of an organic compound were compared in productivities and in the evolution of the crystal size distributions. These shed new light on the underlying mechanisms, drawing attention to the existence of several agonist effects and particularly the role of entrainment in the deracemization process. |
| Databáze: | OpenAIRE |
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