Palladium(II)-acetamide complex as a solid monitoring reagent for carbon monoxide
| Autor: | Yuan C. Chiang, Yun Long. Liaw, Jack L. Lambert, Joseph V. Paukstelis |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Ligand Inorganic chemistry chemistry.chemical_element General Chemistry Chemical reaction Metal chemistry.chemical_compound chemistry visual_art Reagent visual_art.visual_art_medium Environmental Chemistry Compounds of carbon Acetamide Carbon monoxide Palladium |
| Zdroj: | Environmental sciencetechnology. 21(5) |
| ISSN: | 0013-936X |
| Popis: | A study of solid salts containing cationic complexes of palladium(II) with neutral, weakly complexing ligands resulted in the discovery of the palladium(II)-acetamide-tetrafluoroborate reagent, in which acetamide is present in 20-fold molar excess. It was found that a successful reagent of this type must have a ligand that complexes palladium(II) weakly, but more strongly than does water, with water available for subsequent reaction. Carbon monoxide appears to coordinate with the palladium(II)-acetamide complex, which then reacts with water to form, simultaneously, palladium(O) metal that is black, carbon dioxide, and hydrogen ion. The reagent is described as a visual warning device for the present of carbon monoxide. 5 figs., 1 tab. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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