Total syntheses of oxygenated brazanquinones via regioselective homologous anionic Fries rearrangement of benzylic O-carbamates

Autor:	Jari N. Cardoso, Claudio C. Lopes, Rosângela S. C. Lopes, Mariângela Soares de Azevedo, Gláucia B. C. A. Slana
Rok vydání:	2006
Předmět:	Natural product Chemistry Fries rearrangement Stereochemistry Organic Chemistry Regioselectivity Total synthesis Full Research Paper lcsh:QD241-441 chemistry.chemical_compound lcsh:Organic chemistry Organic chemistry lcsh:Q lcsh:Science
Zdroj:	Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Vol 2, Iss 1, p 1 (2006)
ISSN:	1860-5397
DOI:	10.1186/1860-5397-2-1
Popis:	Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from beta-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7aede8fad1c2c611270a88cdf2a57670 https://doi.org/10.1186/1860-5397-2-1 Zobrazit plný text záznamu