Control of Alq3 wetting layer thickness via substrate surface functionalization

Autor: Shufen Tsoi, Michael J. Brett, Bryan Szeto, M. D. Fleischauer, Jonathan G. C. Veinot
Rok vydání: 2007
Předmět:
Zdroj: Langmuir : the ACS journal of surfaces and colloids. 23(12)
ISSN: 0743-7463
Popis: The effects of substrate surface energy and vapor deposition rate on the initial growth of porous columnar tris(8-hydroxyquinoline)aluminum (Alq3) nanostructures were investigated. Alq3 nanostructures thermally evaporated onto as-supplied Si substrates bearing an oxide were observed to form a solid wetting layer, likely caused by an interfacial energy mismatch between the substrate and Alq3. Wetting layer thickness control is important for potential optoelectronic applications. A dramatic decrease in wetting layer thickness was achieved by depositing Alq3 onto alkyltrichlorosilane-derivatized Si/oxide substrates. Similar effects were noted with increasing deposition rates. These two effects enable tailoring of the wetting layer thickness.
Databáze: OpenAIRE