Assembly of fused indenes via Au(I)-catalyzed C1-C5 cyclization of enediynes bearing an internal nucleophile

Autor:	Zhu-Jun Yao, Zhenhua Zhang, Qiwen Hou, Huaqin Wang, Fanji Kong, Shaozhong Wang
Rok vydání:	2012
Předmět:	Bearing (mechanical) Stereochemistry Chemistry Metals and Alloys General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Nucleophile Cascade reaction law Materials Chemistry Ceramics and Composites
Zdroj:	Chemical communications (Cambridge, England). 49(7)
ISSN:	1364-548X
Popis:	A tandem reaction initiated by Au(I)-catalyzed C1–C5 cyclization of enediynes bearing an internal carboxy nucleophile has been developed, providing a distinctive methodology for the assembly of fused indenes including indeno[1,2-c]isochromen-5(11H)-ones and indeno[1,2-b]pyran-2(5H)-ones. A mechanism involving the concerted formation of the five- and six-membered rings was proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a94bba1136283c6517c54636d1f3002 https://pubmed.ncbi.nlm.nih.gov/23223174 Zobrazit plný text záznamu