Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins

Autor:	Sara Gonzalez, Roser Pleixats, Françoise Hénin, Benjamin Ganchegui, Marcial Moreno-Mañas, Jacques Muzart, Jean Le Bras, Mar Tristany, Deb Kumar Mukherjee
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Hydrogen Double bond Atmospheric pressure Inorganic chemistry chemistry.chemical_element General Medicine General Chemistry Tributylamine Toluene Catalysis Solvent chemistry.chemical_compound chemistry Hydrogenolysis Materials Chemistry Palladium
Zdroj:	New J. Chem.. 28:1550-1553
ISSN:	1369-9261 1144-0546
DOI:	10.1039/b409604e
Popis:	Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a90f4b08e385c28befbf560888513a5 https://doi.org/10.1039/b409604e Zobrazit plný text záznamu